Analysis of Antibacterial and Antifungal Properties on the Surface of Acrylic Solid
The antibacterial and antifungal performance of acrylic solid surface is influenced by resin modification technology, types of additives and environmental conditions. The following analysis is conducted from three aspects: antibacterial mechanism, antifungal performance and influencing factors:
First, the sources and mechanisms of antibacterial properties
Antibacterial agent doping
Antibacterial functions can be endowed to the coating by introducing inorganic antibacterial agents (such as zinc oxide, silver ions) or organic antibacterial agents (such as quaternary ammonium salts) into acrylic resin. For instance, zinc oxide can generate photocatalytic activity under ultraviolet light irradiation, releasing zinc ions to destroy the cell membranes of bacteria, thereby inhibiting bacterial proliferation. Experiments show that the acrylic coating containing zinc oxide can still maintain high antibacterial activity after simulating daily wear. The release of zinc ions significantly increases after wear treatment, and the photocatalytic antibacterial effect is outstanding.
Surface modification technology
Grupos antibacterianos são introduzidos na superfície da resina acrílica através de enxerto químico ou mistura física. Por exemplo, a mistura de agentes antibacterianos contendo siloxano com resinas acrílicas pode dotar a superfície do revestimento com hidrofobicidade e propriedades antibacterianas, reduzindo a adesão bacteriana. Além disso, a introdução de agentes nano-antibacterianos (como Nano-Silver) pode melhorar ainda mais o desempenho antibacteriano, mas sua dispersibilidade precisa ser controlada para evitar aglomeração.
Antibacteriano ambientalmente responsivo
Some acrylic coatings can trigger antibacterial mechanisms through environmental stimuli such as humidity and light. For instance, in a humid environment, the release rate of the antibacterial agent in the coating accelerates, thereby enhancing the antibacterial effect. This characteristic is suitable for the antibacterial requirements in high-humidity environments such as bathrooms and kitchens.
Second, the performance and influencing factors of anti-mold performance
Anti-mold mechanism
The anti-mold performance of acrylic coating mainly depends on its dense surface structure and low water absorption rate. For instance, by optimizing the resin formula and curing process, the porosity of the coating surface can be reduced, thereby inhibiting the adhesion and growth of mold spores. In addition, adding fungicides (such as isothiazolinones) can further enhance the anti-mold effect, but attention should be paid to their compatibility with the resin.
The influence of environmental conditions
The growth of mold requires the satisfaction of three elements: moisture, temperature and nutrient substrate. For instance, in an environment with a temperature ranging from 25 to 30℃ and a humidity of ≥80%, the growth rate of mold significantly accelerates. The acrylic coating should have good water resistance and breathability to prevent water accumulation on the surface from causing mold growth. In addition, the pH value of the coating surface also affects the anti-mold performance. A neutral or weakly alkaline environment is more conducive to inhibiting mold growth.
Long-term durability
The anti-mold performance of acrylic coating may decline over time. For instance, in outdoor environments, ultraviolet radiation and rain erosion may cause the coating surface to age and the anti-mold agent to be lost, thereby reducing the anti-mold effect. Therefore, the service life of the coating needs to be prolonged by adding light stabilizers and weather-resistant resins.
Third, the key factors affecting the antibacterial and antifungal performance
Types and dosages of antibacterial agents
The antibacterial effect of inorganic antibacterial agents (such as zinc oxide and silver ions) is long-lasting, but it may affect the transparency and mechanical properties of the coating. Organic antibacterial agents (such as quaternary ammonium salts) have a fast antibacterial speed, but their heat resistance and durability are relatively poor. For instance, excessive silver ion content may cause the coating to discolor, and the addition amount of zinc oxide needs to be controlled at 5-10% to balance the antibacterial performance and coating performance.
Characteristics of resin matrix
A temperatura de transição vítrea (TG) e a densidade de reticulação da resina acrílica afetam a taxa de liberação de agentes antibacterianos. Por exemplo, a resina TG alta pode diminuir a liberação de agentes antibacterianos e prolongar o efeito antibacteriano; A reticulação moderada pode aumentar a densidade do revestimento e reduzir a adesão do mofo. Além disso, quanto mais forte a hidrofobicidade da resina, melhor seu desempenho anti-molde.
Condições de construção e cura
A temperatura e a umidade do ambiente de construção afetam o efeito de cura e o desempenho antibacteriano e antifúngico do revestimento. Por exemplo, a cura sob condições de baixa temperatura ou alta umidade pode levar a estresse interno desigual no revestimento, reduzindo sua durabilidade. Além disso, o tempo de cura e a intensidade da luz também afetarão o efeito de reticulação e fixação do agente antibacteriano.
Quarto, cenários de aplicação de desempenho antibacteriano e antifúngico
Instalações médicas
Os requisitos de desempenho antibacteriano para revestimentos em enfermarias hospitalares, salas de operações e outros lugares são extremamente altas. Por exemplo, revestimentos antibacterianos acrílicos podem ser aplicados a paredes e superfícies de móveis para reduzir o risco de transmissão bacteriana. Tais revestimentos precisam ter propriedades antibacterianas altamente eficientes (como uma taxa de inibição ≥99% contra Escherichia coli e Staphylococcus aureus) e durabilidade a longo prazo.
Planta de processamento de alimentos
Mold contamination in the food processing environment must be strictly controlled. For instance, acrylic anti-mold coating can be applied to workshop walls and equipment surfaces to prevent mold growth and food contamination. Such coatings need to have chemical resistance (such as resistance to acids, alkalis, and cleaning agents) and low VOC emissions to meet food safety requirements.
Public buildings
The walls and floors in public places such as schools and shopping malls are prone to microbial contamination. For instance, acrylic antibacterial and anti-mold coatings can be applied to frequently touched areas such as bathrooms and elevator buttons, reducing the risk of cross-infection. Such coatings need to be wear-resistant and easy to clean in order to maintain long-term antibacterial effects.
Fifth, strategies for enhancing antibacterial and antifungal performance
Composite antibacterial system
By compounding inorganic antibacterial agents with organic antibacterial agents, a broad-spectrum antibacterial effect can be achieved. For example, the synergistic effect of zinc oxide and quaternary ammonium salt antibacterial agents can simultaneously inhibit the growth of bacteria and molds. In addition, the addition of photocatalysts (such as titanium dioxide) can enhance the photocatalytic antibacterial performance of the coating.
Surface microstructure control
By regulating the microscopic morphology of the coating surface (such as roughness and porosity), the adhesion of microorganisms can be reduced. For instance, the application of superhydrophobic surface technology can make the contact Angle of the coating surface ≥150°, thereby inhibiting the adhesion of mold spores. In addition, surface patterning design can also reduce the contact area for microorganisms.
Long-lasting anti-mold technology
The action time of fungicides is prolonged through slow-release technology. For instance, fungicides can be encapsulated in microcapsules, allowing them to be gradually released during the application of the coating, thereby maintaining a long-term fungicidal effect. In addition, adding self-healing materials can enable the coating to automatically repair itself after being damaged and restore its anti-mold performance.
